Thermodynamic cycles and the Carnot Cycle
A description of thermodynamic cycles and in particular the Carnot Cycle and the proof of it's thermal efficiency
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Thermodynamic Cycles
A series of operations carried out on the Working Substance (WS) during which heat is supplied (Q) . There is a work output (W) after which the WS is returned to it's original state.
Expansion from

to

and a Work Ouput of
Compression from

to

and a Work input of
The First Law Applied To A Cycle:
- By Definition:
The Energy of the WS at the start of the cycle + Heat supplied = Energy of the WS at the end of the cycle + WD +Heat losses.
or Work output = Heat supplied - Heat lost and rejected.
Drawing the cycle on a T
diagram
Heat supplied,
, increasing
Heat rejected,
decreasing
Area of diagram =
-
= Work Done
NOTE: the area of the P V diagram gives the Work Done in ft lbs. The area of the T
diagram gives the work Done in BTUs
The Thermal Efficiency Of A Cycle:
-
therefore
Carnot Cycle
We can obtain the efficiency of the
Carnot Cycle and hence the efficiency of
any Reversible cycle operating between the temperatures of

and

. This then represents the
Ultimate Thermal Efficiency. This is then used to compare the efficiencies of other cycles operating between the same two temperatures. The importance of the Carnot Cycle in this role can not be under estimated.
Stage 1 to 2
- Reversible adiabatic i.e.isentropic, compression of WS from
to
Stage 2 to 3
- Isothermal heating with expansion.
Stage 3 to 4
- Adiabatic (reversible) isentropic expansion of WS from
to
Stage 4 to 1
- Isothermal cooling with Compression.
The cycle can also be expressed on a T

diagram.
The Efficiency of the
Carnot Cycle
therefore
But from the
T Q Diagram
Therefore
To Improve Efficiency
- Increase the value of
- Lower the general level of Temperature.
It is more advantageous to lower the temperature at which heat is rejected than to raise the temperature at which it is supplied.
The
available Energy is
Example 1:
- The efficiency of a steam Engine is 52% of the Carnot Efficiency if the steam is supplied at
and condensed at
. Find the heat required to produce 1 HP for 1 minute.
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